Product ID:48102, VOA MATRIX SPIKE MIX, 1X1ML, MEOH (SUP DAT)
MSDS Date:03/14/1994
FSC:6630
NIIN:00N066612
MSDS Number: CBDSX

SUPELCO INC

SUPELCO PARK
BELLEFONTE, PA 16823-0048
US

Emergency Phone: 814-359-3441

Info Phone: 814-359-3441

Cage: 54968

SIGMA-ALDRICH INC.

14508 ST. LOUIS, MO 63103 US

Telephone: 314-771-5765/414-273-3850X5996

Cage: 54968

BENZENE, CHLORO-; (CHLOROBENZENE) (SARA 313) (CERCLA)

CAS: 108-90-7

RTECS: CZ0175000

Fraction By Weight: 0.1%

OSHA PEL 75 PPM

ACGIH TLV: 10 PPM

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

ETHYLENE, 1,1-DICHLORO-; (VINYLIDENE CHLORIDE) (CERCLA)

CAS: 75-35-4

RTECS: KV9275000

Fraction By Weight: 0.1%

OSHA PEL 1 PPM

ACGIH TLV: 5 PPM/20 STEL

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

ETHYLENE, TRICHLORO-; (TRICHLOROETHYLENE) (SARA 313)

CAS: 79-01-6

RTECS: KX4550000

Fraction By Weight: 0.1%

OSHA PEL 100 PPM

ACGIH TLV: 50 PPM/100STEL,A5

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

5628 MG/KG

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 99-100%

OSHA PEL S, 200 PPM

ACGIH TLV: S,200PPM/250STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

4894 MG/KG

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: 0.1%

OSHA PEL SEE 1910.1028

ACGIH TLV: 10 PPM; A2

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

TOLUENE; (BENZENE, METHYL-TOLUENE) (SARA 313) (CERCLA)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 0.1%

OSHA PEL 200 PPM

ACGIH TLV: S, 50 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:SEE INGREDIENTS.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:HARMFUL IF INHALED. MAY BE FATAL IF
SWALLOWED. CONTAINS MATERIAL(S) KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE CANCER. HEADACHE, NAUSEA, GASTROINTESTINAL DISTURBANCES,
BLINDNESS, LEUKEMIA. TOLUENE APPE ARS ON NAVY LISTING OF OCCUP CHEM
REPROHAZS. SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS (EFTS
OF OVEREXP)
Explanation of Carcinogenicity:BENZENE:IARC MONOGRAPHS, SUPP, VOL 7, PG
120, 1987:GROUP 1. NTP 7TH ANNUAL RPT ON CARCINS, 1994:KNOWN TO BE
(SUPP DATA)
Effects of Overexposure:HLTH HAZS:CONCERNING LASTEST HAZARD LIST
INFORMATION AND SAFE HANDLING AND EXPOSURE INFORMATION .
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES:FLUSH W/WATER FOR @ LST 15 MIN. CONT MD. SKIN:FLUSH W/LG
VOLS OF WATER. INHAL:IMMED MOVE TO FRESH AIR. IF BRTHG STOPS, GIVE
ARTF RESP. CONT MD. INGEST:NEVER GIVE ANYTHING BY MOUTH TO AN UNCON
PER SON. NEVER TRY TO MAKE AN UNCON PERSON VOMIT. GIVE 2 TBLS OF
BAKING SODA IN GLASS OF WATER. PRESS FINGERS TO BACK OF TONGUE TO
INDUCE VOMIT. IMMED CONT MD.

Flash Point:50.0F,10.0C
Lower Limits:6.0%
Upper Limits:36%
Extinguishing Media:CO*2, DRY CHEMICAL, ALCOHOL FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:THE FOLLOWING TOXIC VAPORS ARE FORMED
WHEN THIS MATERIAL IS HEATED TO DECOMPOSITION. HYDROGEN CHLORIDE.

Spill Release Procedures:TAKE UP WITH ABSORBENT MATERIAL. VENTILATE
AREA. ELIMINATE ALL IGNITION SOURCES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:REFRIGERATE IN SEALED CONTAINER. KEEP
AWAY FROM OXIDIZERS. KEEP AWAY FROM IGNITION SOURCES.
Other Precautions:AVOID EYE OR SKIN CONTACT. AVOID BREATHING VAPORS.

Respiratory Protection:WEAR NIOSH/MSHA APPROVED FACE MASK WITH ORGANIC
VAPOR CANISTER.
Ventilation:USE ONLY IN WELL VENTILATED AREA.
Protective Gloves:WEAR RUBBER GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:ANSI APPROVED EMERGENCY EYE WASH AND DELUGE
SHOWER .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MFR TRADE/PART NO:1000UG/ML EACH. EXPLAN OF CARCIN:CARCINOGEN. FEDERAL
REGISTER, VOL 52, PG 34460, 1987:OSHA-CANCER HAZARD. HUMAN:MYELOID
LEUKEMIA, HODGKINS DISEASE, LYMPHOMA.

Boiling Pt:B.P. Text:149F,65C
Melt/Freeze Pt:M.P/F.P Text:-144F,-98C
Vapor Pres:100
Vapor Density:1.10
Spec Gravity:0.790 (H*2O=1)
Evaporation Rate & Reference:>1 (ETHER=1)
Solubility in Water:100
Appearance and Odor:CLEAR, COLORLESS LIQUID.
Percent Volatiles by Volume:10

Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS, CHROMIC ANHYDRIDE, LEAD PERCHLORATE, PERCHLORIC
ACIDS.
Hazardous Decomposition Products:HYDROGEN CHLORIDE.

Waste Disposal Methods:COMPLY WITH ALL APPLICABLE FEDERAL, STATE OR
LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.